6-Bromo-2-naphthol–piperazine (2/1)

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6-Bromo-2-naphthol–piperazine (2/1)

In the title compound, 2C(10)H(7)BrO·C(4)H(10)N(2), the piperazine (pip) mol-ecule displays a chair conformation and is linked to two mol-ecules of 6-bromo-2-naphthol (bno) via O-H⋯N hydrogen bonds. Weak N-H⋯O hydrogen bonds from pip to bno mol-ecules result in chains propagating in [100]. The chains inter-act via C-H⋯π inter-actions.

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The title compound, C(13)H(15)BrClNO, was prepared by the condensation of equimolar quanti-ties of 3-bromo-5-chloro-salicyl-aldehyde with cyclo-hexyl-amine in methanol. There is an intra-molecular O-H⋯N hydrogen bond in the mol-ecule. The cyclo-hexyl ring adopts a chair conformation.

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6-Bromo-2-methyl­sulfanyl-1,3-benzo­thia­zole

The title mol-ecule, C(8)H(6)BrNS(2), is almost planar with a dihedral angle of 0.9 (1)° between the benzene and thia-zole rings. The values of the geometry-based index of aromaticity (HOMA) and the nucleus-independent chemical shift (NICS) for the two cyclic fragments of the title mol-ecule are 0.95 and -9.61, respectively, for the benzene ring, and 0.69 and -7.71, respectively, for the thia-z...

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6-Bromo-1,3-benzothia­zol-2-amine

The r.m.s. deviation from the mean plane for the non-H atoms in the title compound, C(7)H(5)BrN(2)S, is 0.011 Å. In the crystal, the mol-ecules are linked by N-H⋯N and N-H⋯Br hydrogen bonds to generate (010) sheets. Weak aromatic π-π stacking [centroid-to-centroid separation = 3.884 (10) Å] and possible C-H⋯Br inter-actions are also observed. The crystal studied was found to be an inversion twin.

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2-Benzyl­imino­meth­yl-6-bromo-4-chloro­phenol

The title mol-ecule, C(14)H(11)BrClNO, adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic rings is 70.4 (5)°. An intra-molecular O-H⋯N hydrogen bond is observed between the hydroxyl and imine groups.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808036878